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Residual herbicides - carryover and behaviour in dry conditions

The term 'residual' applies to herbicides that have long-lasting activity in the soil. These herbicides are often applied directly to the soil prior to (that is, pre-emergent) planting crops.  

 

Residual herbicides break down with moisture and microbial activity. A consequence of a drier than average growing season is that herbicides applied may still be active in the following season because conditions have not facilitated the break down.

In addition, residual herbicides can be applied in advance of dry sown crops and still be expected to have sufficient weed control activity when the season breaks. 

Testing for residual herbicides can indicate whether you should plant a crop that is more tolerant to the residual herbicide. 

Carryover of residual herbicides from season to season 

A consequence of a growing season being drier than average, particularly in the eastern and northern Western Australia (WA) grainbelt, is that herbicides applied in one season could still have significant residues in the soil and affect crops planted the following year. 

Sulfonylurea (SU), imidazolinone (IMI), and triazine herbicides are likely to cause the most concern. Residues from the previous season may affect crop emergence or even kill sensitive crops or crop cultivars in the next season. 

Following dry years, damage symptoms have been reported on canola crops where diflufenican products were applied to prior lupin crops, or diflufenican/MCPA or diflufenican/bromoxynil were applied in wheat crops. 

Fomesafen (for example, Reflex®) at the product rates 1 to 1.5 L/ha, used on sandy-to-sandy loam soils that are low in organic carbon (OC) (0.5 to 1.5%), and/or non-wetting soils, could pose residue issues to succeeding cereals crops. If planning to grow cereals after lupins on such soil types, use lower rate of fomesafen at 750 mL/ha in lupins to avoid residue issues. Do not use fomesafen on soils that have less than 0.5% organic carbon.  

Clopyralid used on canola and cereals could pose a risk of carryover both in soil and plant residues/stubbles for subsequent susceptible legume crops. 

The soil pH will impact which herbicides are more likely to persist. All other things being equal, imidazolinones will be more persistent on acid soils and sulphonyl ureas on alkaline soils. Triazines are very slightly more persistent on alkaline soils. 

Dry conditions reduce herbicide degradation 

The main factors contributing to residue carryover are poor uptake of herbicides by crop plants and limited microbial or chemical degradation of herbicides in dry soil conditions. 

For simazine to be absorbed by plants, the required water content is 5% in sandy soils and 10 to 15% in heavy soils. Simazine has a half-life of 3 to 6 months during winter. Half-life is the length of time it takes for the effectiveness of the herbicide to reduce by half. 

In an average year, at least 95% of simazine applied in the crop will be degraded by the end of the season. Any remaining simazine will have no effect on the following crops. 

The presence of root diseases in a cereal crop may exacerbate the effects of herbicide residues. 

Summer rain can aid the breakdown of residues if the soil surface remains wet long enough for breakdown processes to occur. 

In some instances, where there are large downpours of rain that infiltrate through the soil profile, the water may move soluble residues (such as the SU’s) down the profile. This may be an issue of concern on duplex soils, where crop damage symptoms do not appear until the roots reach the zone where the residues have moved to. 

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